New Mechanism Reveals Optical Activity in Non-Chiral Crystals
Achiral crystal reveals Raman optical activity through ferroaxial order
Phys.org
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Researchers at the Institute of Science Tokyo have demonstrated Raman optical activity in an achiral, nonmagnetic crystal, nickel titanium oxide, through ferroaxial order. This discovery challenges existing notions of optical activity, revealing that even optically inactive materials can exhibit chirality-like responses.
- 01Raman optical activity (ROA) has been observed in nickel titanium oxide (NiTiO3), which is achiral and nonmagnetic.
- 02The effect arises from ferroaxial order, a coordinated rotation of atoms, rather than traditional chiral or magnetic properties.
- 03The findings were led by Professor Takuya Satoh and published in Physical Review Letters on May 19, 2026.
- 04Circularly polarized Raman spectroscopy revealed differences in light scattering intensity, indicating ROA in non-chiral materials.
- 05This research expands the understanding of optical activity and may lead to new materials discovery and measurement techniques.
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Researchers at the Institute of Science Tokyo have made a groundbreaking discovery by demonstrating Raman optical activity (ROA) in an achiral, nonmagnetic crystal, specifically nickel titanium oxide (NiTiO3). Traditionally, ROA was believed to only occur in chiral molecules or materials exhibiting magnetic order. However, this study reveals that ROA can arise from a structural property known as ferroaxial order, which involves coordinated atomic rotations within the crystal lattice. The research team, led by Professor Takuya Satoh, used circularly polarized Raman spectroscopy to detect differences in the intensity of scattered light between left- and right-circularly polarized light, a hallmark of ROA. This effect was found to depend on the orientation of the crystal, indicating that the internal rotational order, rather than chirality, drives the observed optical activity. The findings, published in Physical Review Letters, challenge conventional views and suggest that optically inactive materials can exhibit chirality-like optical responses, paving the way for new optical measurement techniques and material discoveries.
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This discovery could lead to advancements in optical measurement techniques and the development of new materials with unique properties.
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